Free Software licenses only apply to the source code, not binaries. And, depending on the license, you might also be allowed to make a closed source UI or shell on top of the software.
Why would you purchase it?
Because you want a nice supported easy to install version compiled and packaged for your platform
Doesn't work, unless you're a registered developer and can sign it by yourself. Personally I haven't felt in the mood to do that just for installing an app. On Android it is way easier - you just click a checkbox in its settings, then download the apk.
Why would you purchase it? And who gets the money when you do?