Actually, all consumers of free online courses are charity cases. Deaf people are suing because MIT's and Harvard's largesse doesn't always include them.
MIT and Harvard's "largess" is funded in part by tax money collected from deaf people. Anyway, donating to a a discriminatory cause is still discrimination even if it is generous or well-intentioned.
So what about any charitable effort that discriminates on the basis of a protected class. If you can't do something for free to help one group without excluding some others no charity would be possible. Should MIT/Harvard intentionally avoid captioning? No. Should the government force them to use CCing? Hell no.
Your charitable cause is putting some people at a disadvantage then. If your charitable effort somehow must discriminate, it should do it in favor of the less-privileged group.