Neither one really has a direct "equivalent" in assembly.
Prefix is going to look something like:
inc eax # increment the value
mov eax,ecx # copy the return value to its destination
Postfix is going to look something like:
mov eax,ebx # copy original value
inc eax # increment value
mov ebx,ecx # copy original value to final destination
The actual code you'd get would vary a lot between compilers, architectures, and even just different contexts within the same compiler-architecture combination.
Is there an equivalent instruction in assembly for postfix increment/decrement?