The separation isn't perfect, but the first vapors of distillation (the heads) are discarded precisely because they have a higher concentration of methanol.
Methanol boils at 65 C, ethanol at 78. Again, you wont get a perfect separation, but there's enough of a difference that you can get rid of a fair amount.
Methanol boils at 65 C, ethanol at 78. Again, you wont get a perfect separation, but there's enough of a difference that you can get rid of a fair amount.