> The argument generally is that warming temperatures cause rising CO2. This in turn is a fact not disputed by climate scientists, only that it is not sufficient to explain the current rise in CO2.
It should also be noted that the type of C in CO2 matters:
> In addition, only fossil fuels are consistent with the isotopic fingerprint of the carbon in today’s atmosphere. Different kinds of carbon-containing material have different relative amounts of “light” carbon-12, “heavy” carbon-13, and radioactive carbon-14. Plant matter is enriched in carbon-12, because its lighter weight is more readily used by plants during photosynthesis. Volcanic emissions are enriched in carbon-13. The ratio of carbon-13 to carbon-12 in the atmosphere and the ocean are roughly the same. Since carbon-14 is radioactive, it decays predictably over time. Young organic matter has more carbon-14 than older organic matter, and fossil fuels have no measurable carbon-14 at all.
> As carbon dioxide concentrations in the atmosphere have risen over the past century or more, the ratio of carbon-13 to carbon-12 has fallen, which means that the source of the extra carbon dioxide must be enriched in "light" carbon-12. Meanwhile, the relative amount of carbon-14—radioactive carbon—has declined. The record of carbon-14 in the atmosphere is complicated by nuclear bomb testing after 1950, which doubled the amount of radioactive carbon in the atmosphere. After the nuclear test ban treaty in 1963, the excess atmospheric carbon-14 began to decline as it dispersed into the oceans and the land biosphere.
> In this “Grand Challenges” paper, we review how the carbon isotopic composition of atmospheric CO2 has changed since the Industrial Revolution due to human activities and their influence on the natural carbon cycle, and we provide new estimates of possible future changes for a range of scenarios. Emissions of CO2 from fossil fuel combustion and land use change reduce the ratio of 13C/12C in atmospheric CO2 (δ13CO2). This is because 12C is preferentially assimilated during photosynthesis and δ13C in plant-derived carbon in terrestrial ecosystems and fossil fuels is lower than atmospheric δ13CO2. Emissions of CO2 from fossil fuel combustion also reduce the ratio of 14C/C in atmospheric CO2 (Δ14CO2) because 14C is absent in million-year-old fossil fuels, which have been stored for much longer than the radioactive decay time of 14C.
It should also be noted that the type of C in CO2 matters:
> In addition, only fossil fuels are consistent with the isotopic fingerprint of the carbon in today’s atmosphere. Different kinds of carbon-containing material have different relative amounts of “light” carbon-12, “heavy” carbon-13, and radioactive carbon-14. Plant matter is enriched in carbon-12, because its lighter weight is more readily used by plants during photosynthesis. Volcanic emissions are enriched in carbon-13. The ratio of carbon-13 to carbon-12 in the atmosphere and the ocean are roughly the same. Since carbon-14 is radioactive, it decays predictably over time. Young organic matter has more carbon-14 than older organic matter, and fossil fuels have no measurable carbon-14 at all.
> As carbon dioxide concentrations in the atmosphere have risen over the past century or more, the ratio of carbon-13 to carbon-12 has fallen, which means that the source of the extra carbon dioxide must be enriched in "light" carbon-12. Meanwhile, the relative amount of carbon-14—radioactive carbon—has declined. The record of carbon-14 in the atmosphere is complicated by nuclear bomb testing after 1950, which doubled the amount of radioactive carbon in the atmosphere. After the nuclear test ban treaty in 1963, the excess atmospheric carbon-14 began to decline as it dispersed into the oceans and the land biosphere.
* https://www.climate.gov/news-features/climate-qa/how-do-we-k...
> In this “Grand Challenges” paper, we review how the carbon isotopic composition of atmospheric CO2 has changed since the Industrial Revolution due to human activities and their influence on the natural carbon cycle, and we provide new estimates of possible future changes for a range of scenarios. Emissions of CO2 from fossil fuel combustion and land use change reduce the ratio of 13C/12C in atmospheric CO2 (δ13CO2). This is because 12C is preferentially assimilated during photosynthesis and δ13C in plant-derived carbon in terrestrial ecosystems and fossil fuels is lower than atmospheric δ13CO2. Emissions of CO2 from fossil fuel combustion also reduce the ratio of 14C/C in atmospheric CO2 (Δ14CO2) because 14C is absent in million-year-old fossil fuels, which have been stored for much longer than the radioactive decay time of 14C.
* https://agupubs.onlinelibrary.wiley.com/doi/full/10.1029/201...