It's a rocket so there is always a non-zero risk of explosion. This one is also a new, not-yet-launched rocket, making it extra non-zero chance of explosion.
Its and apples and oranges comparison of combustion chambers. For purposes of combustion, the relavant pressure is the exaust of the rocket engine where combusion is complete. The burning gas within an ic engine is, at the point of combusion, at a very higher pressure. The ic equivalent of a rocket combusion chamber would be the blast wave starting at the spark, which then moves through the fuel. This difference become more important when discussing the new tech of pulse detonation rocket engines.