the batteries explode because of the materials in them, not because of the stored electrical energy. An full lithium battery wouldn't explode much more violently than an empty one.
I fly FPV so I deal with exploding batteries from time to time. Fully charged batteries explode much more violently than discharged batteries which tend to smolder instead. I suspect the additional electric discharge is adding ‘fuel to the fire.’
Interestingly, a discharged lithium ion battery still has electric potential in it, it's just that we stop discharging it after it hits a cutoff voltage to protect the battery's lifespan.
I wonder if a truly 100% discharged battery (down to zero volts) would actually be basically inert, and not even smolder if you poked it.
Lithium Ion batteries do burn much more readily when fully charged than when discharged -- this is because they self-discharge rapidly at elevated temperatures, which provokes an even greater reaction of the materials inside of them. Specifically, if the cathode of NMC/NCA batteries gets hot enough, it will decompose into oxygen and really kick off the graphite + electrolye burning.
Discharged batteries are tougher to get to burn since it's harder to heat the cathode to that point externally so oxygen has to come from the environment.
This is not correct and is against basic thermodynamics and conservation of energy. Store a whole bunch of potential energy somewhere and you have an explosive. The more stored energy of any form, the bigger the boom.
