I'm real curious as to which hybrids you've been taking trips in. A gen 4 Prius can easily do 600 miles at highway speed. A gen 3 should be able to do at least 550 on a full tank. That's nearly 8 hours at 70mph.
The Prius Prime is the PHEV version, which is more expensive than the standard Prius. It has the same gas engine and nearly the same gasoline range as the standard Prius (it gets slightly lower MPG due to the increased weight). You're obviously not going to get far on battery power alone, that is about 25 miles. The intention was to be able to cover a typical commute to work, and then be able to charge a work.
Just read a little bit on the 330e. It doesn't get nearly as good gas mileage as a Prius, but is obviously a much peppier car.
Though if I was spending that much money, I'd try to get a Rav4 Prime, which is nearly as quick (5.7 seconds for 0-60 mph), 600 mile range, and all wheel drive. But that's a personal preference, I'm not in the market for a sports sedan.
There's no current EV that can do that.