Water has very high thermal mass, is indexpensive, non-toxic, non-corrosive, and multi-use. Its liquid temperature range corresponds well (for evident reasons) to living conditions.
There are phase-change and transformational materials. Most complicate the process markedly, and may degrade (through loss or contamination) over time.
Only liquid-solid phase-chane is likely to be useful as liquid-gas volumetric expansion tends to 1:1000, leading to very large volume, or high pressure, or both, considerations, with corresponding costs and risks.
Aqueous thermal storage is remarkably inert. Small leaks are harmless, large leaks leave no long-term toxic legacy, pressures are ambient, materials are mundane, systems, monitoring, and controls simple, well-developed, and well-understood.
There are phase-change and transformational materials. Most complicate the process markedly, and may degrade (through loss or contamination) over time.
Only liquid-solid phase-chane is likely to be useful as liquid-gas volumetric expansion tends to 1:1000, leading to very large volume, or high pressure, or both, considerations, with corresponding costs and risks.
Aqueous thermal storage is remarkably inert. Small leaks are harmless, large leaks leave no long-term toxic legacy, pressures are ambient, materials are mundane, systems, monitoring, and controls simple, well-developed, and well-understood.