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I'll second Thinking, Fast and Slow by Daniel Kahneman for top book of 2012 and for top all time book like another commenter.

If you really want to expose the bias and structure of your consciousness, this the book to read. I would also pair this book with Incognito by David Eagleman (2012) to rehash some of the ideas of Kahneman and for a discussion of the implications of these ideas in morals and justice.

Also Connectome by Sebastian Seung (2012) gives a good outline of the structure of the brain, and an interesting discussion of how understanding that structure is a great scientific goal and some hypothetical implications of that understanding.

Really, I'd recommend reading anything to do with the emerging understanding of the brain because, without hyperbole, the better we understand the brain the better we understand the self.

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