Based on the resources I can find online, any select-by-range operation in Riak requires broadcasting to all nodes (or at least enough nodes to hit at least one replica of each record), and then performing a scatter-gather operation to fetch the matching records. There also doesn't seem to be any way to specify a sorting order. This is not quite what I would call a range scan: while useful, it presumably doesn't have the same cost or scaling characteristics. It's the difference between scanning a block of data that is stored contiguously, and filtering through an entire table to identify records meeting a criterion which happens to take the form "a <= value <= b".
This is not to diss Riak, which is a nice piece of work and does many things that DynamoDB doesn't.