Also, it might be better to swith to email to debug this. I'm available at email@example.com
It doesn't work for me as well (Macbook / Lion 10.7.1). I DON'T see "com.radiosilenceapp.nke.PrivateEye" listed as well.
I haven't moved the app to a different folder.
Do let us know if this is resolved.
* Edit: I also emailed everyone who had contacted me about this.
com.apple.kextd: Can't load /Applications/Private Eye.app/Contents/Resources/Private Eye.kext - no code for running kernel's architecture.
my MBP is from 2006 so my kernel is still 32-bit